Abstract: In this paper, the first synthesis of high molecular weight anionic emulsion, and then join the amino monomer, "capped" and thermodynamic equilibrium is reached before the end of the response, prepared by high molecular weight, amino-modified silicone anionic emulsion. The results show that: the solid content of 15%; single pre-emulsification again dropping; TX-10 non-ionic surfactant under the conditions of access to the oil market molecular weight than similar products about twice as high, and the fabric hand assessment, Smooth and prominent. on this basis, will be the synthesis of latex and epoxy coupling agent, catalyst configured to smoothing agent, used in three-dimensional hollow polyester staple of the smooth finishing. and discussed the amino content, the amount of catalyst, the amount of crosslinker smooth, soft and fluffy of the impact. The results show that: when amino content of 6 percent, catalyst of 1 percent, crosslinker content of 0.25 percent, get better results, compared with similar foreign products with the same level, while a similar market-modified anionic latex compound, the molecular weight of small, slippery and fastness of a clear gap.
Keywords:Silicone; Anionic emulsion copolymerization; Kinetic model ; Oetamethyl cyclotetra siloxane;