Abstract: This article shows particular description of Fabricating Soluble Carbon Nanotubes with Ferrocene or Pyrene Containing Poly(1-alkyl)alkynes. Through physical mixing, highly soluble CNTs hybrids were fabricated. In order to obtain high-performance solubilizers, it is much more important for us to know the relationships between the structure of the polyenes and their solvating power. We can obtain functional hybrids with expected properties and desired high solubility through properly molecular structure design. The polymers and hybrids were also characterized by FT-IR, NMR, UV, TGA, TEM and so on. The results show that the hybrids are thermal stable, solvents redispersible and light emitting. it indicate the potential applications in polymer-based composite materials.